AU609529B2 - Improved process for the manufacture of 1,1,1- trifluorodichloroethane and 1,1,1,2-tetrafluorochloroethane - Google Patents
Improved process for the manufacture of 1,1,1- trifluorodichloroethane and 1,1,1,2-tetrafluorochloroethane Download PDFInfo
- Publication number
- AU609529B2 AU609529B2 AU24115/88A AU2411588A AU609529B2 AU 609529 B2 AU609529 B2 AU 609529B2 AU 24115/88 A AU24115/88 A AU 24115/88A AU 2411588 A AU2411588 A AU 2411588A AU 609529 B2 AU609529 B2 AU 609529B2
- Authority
- AU
- Australia
- Prior art keywords
- tetrahaloethylene
- trifluorodichloroethane
- tetrafluorochloroethane
- seconds
- pentahaloethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims description 28
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 title claims description 12
- BOUGCJDAQLKBQH-UHFFFAOYSA-N 1-chloro-1,2,2,2-tetrafluoroethane Chemical compound FC(Cl)C(F)(F)F BOUGCJDAQLKBQH-UHFFFAOYSA-N 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title description 14
- 238000006243 chemical reaction Methods 0.000 claims description 21
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000003682 fluorination reaction Methods 0.000 claims description 9
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 claims description 8
- 229950011008 tetrachloroethylene Drugs 0.000 claims description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 7
- 229910052700 potassium Inorganic materials 0.000 claims description 7
- 239000011591 potassium Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 238000000197 pyrolysis Methods 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 3
- 239000007792 gaseous phase Substances 0.000 claims description 3
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 3
- 241001482237 Pica Species 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- DIWKDXFZXXCDLF-UHFFFAOYSA-N chloroethyne Chemical compound ClC#C DIWKDXFZXXCDLF-UHFFFAOYSA-N 0.000 claims 1
- 238000004817 gas chromatography Methods 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 24
- 239000000047 product Substances 0.000 description 17
- 239000011651 chromium Substances 0.000 description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- QDOXWKRWXJOMAK-UHFFFAOYSA-N chromium(III) oxide Inorganic materials O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 8
- 239000000376 reactant Substances 0.000 description 7
- JOSWYUNQBRPBDN-UHFFFAOYSA-P ammonium dichromate Chemical compound [NH4+].[NH4+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O JOSWYUNQBRPBDN-UHFFFAOYSA-P 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910001026 inconel Inorganic materials 0.000 description 2
- 229910001507 metal halide Inorganic materials 0.000 description 2
- 150000005309 metal halides Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- DASQIKOOFDJYKA-UHFFFAOYSA-N CCIF Chemical compound CCIF DASQIKOOFDJYKA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 101000601610 Drosophila melanogaster Heparan sulfate N-sulfotransferase Proteins 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 125000004773 chlorofluoromethyl group Chemical group [H]C(F)(Cl)* 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- QCMJBECJXQJLIL-UHFFFAOYSA-L chromium(6+);oxygen(2-);difluoride Chemical compound [O-2].[O-2].[F-].[F-].[Cr+6] QCMJBECJXQJLIL-UHFFFAOYSA-L 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 150000005826 halohydrocarbons Chemical class 0.000 description 1
- 229910000856 hastalloy Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical compound FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- BNIXVQGCZULYKV-UHFFFAOYSA-N pentachloroethane Chemical compound ClC(Cl)C(Cl)(Cl)Cl BNIXVQGCZULYKV-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
- C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/111,292 US4843181A (en) | 1987-10-22 | 1987-10-22 | Process for the manufacture of 1,1,1-trifluorodichloroethane and 1,1,1,2-tetrafluorochloroethane |
| US111292 | 1987-10-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2411588A AU2411588A (en) | 1989-04-27 |
| AU609529B2 true AU609529B2 (en) | 1991-05-02 |
Family
ID=22337652
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU24115/88A Ceased AU609529B2 (en) | 1987-10-22 | 1988-10-21 | Improved process for the manufacture of 1,1,1- trifluorodichloroethane and 1,1,1,2-tetrafluorochloroethane |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4843181A (en]) |
| EP (1) | EP0313061B1 (en]) |
| JP (1) | JPH01146832A (en]) |
| KR (1) | KR890006550A (en]) |
| CN (1) | CN1014988B (en]) |
| AU (1) | AU609529B2 (en]) |
| BR (1) | BR8805440A (en]) |
| CA (1) | CA1310022C (en]) |
| DE (1) | DE3887625T2 (en]) |
| ES (1) | ES2063750T3 (en]) |
| IN (1) | IN171034B (en]) |
| MX (1) | MX165875B (en]) |
| RU (1) | RU2007380C1 (en]) |
| ZA (1) | ZA887889B (en]) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU630807B2 (en) * | 1990-05-11 | 1992-11-05 | Atochem | Process for the manufacture of 1,1,1,2-tetra-fluorochloroethane and/or pentafluoroethane |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5262574A (en) * | 1987-03-09 | 1993-11-16 | Ausimont S.P.A. | Process for preparing 1,1,1-trifluoro-2,2-dichloroethane by hydrofluorination in the presence of catalysts |
| IT1202652B (it) * | 1987-03-09 | 1989-02-09 | Ausimont Spa | Processo per la preparazione di 1,1,1-trifluoro-2,2-dicloroetano mediante idrofluorurazione in presenza di catalizzatori |
| US5276224A (en) * | 1987-03-09 | 1994-01-04 | Ausimont S.P.A. | Process for preparing 1,1,1-trifluoro-2,2-dichloroethane by hydrofluorination in the presence of catalysts |
| CA1310335C (en) * | 1988-02-12 | 1992-11-17 | Leo E. Manzer | Gas-phase fluorination process |
| IN172054B (en]) * | 1988-02-24 | 1993-03-27 | Du Pont | |
| IN171977B (en]) * | 1988-06-29 | 1993-02-27 | Du Pont | |
| US5036036A (en) * | 1989-06-13 | 1991-07-30 | E. I. Du Pont De Nemours And Company | Chromium oxide catalyst composition |
| IT1230779B (it) * | 1989-07-12 | 1991-10-29 | Ausimont Srl | Procedimento per preparare 1,1,1,2 tetrafluoroetano. |
| US5045634A (en) * | 1990-06-28 | 1991-09-03 | E. I. Du Pont De Nemours And Company | Fluorination of haloolefins |
| US5030372A (en) * | 1990-07-31 | 1991-07-09 | E. I. Du Pont De Nemours And Company | Catalytic equilibration to improve the relative yield of selected halocarbons |
| US5177273A (en) * | 1991-02-01 | 1993-01-05 | E. I. Du Pont De Nemours And Company | Process for the manufacture of halogen-substituted propanes containing hydrogen and at least five fluorine substituents |
| ZA923274B (en) * | 1991-05-06 | 1993-11-08 | Du Pont | Process for the manufacture of pentafluoroethane |
| EP0584282B1 (en) | 1991-05-06 | 1999-01-20 | E.I. Du Pont De Nemours And Company | Process for the manufacture of pentafluoroethane |
| US5182042A (en) * | 1991-10-21 | 1993-01-26 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1,1-trifluorohexane and perfluoromethylcyclohexane |
| US5569797A (en) * | 1992-01-07 | 1996-10-29 | E. I. Du Pont De Nemours And Company | Method of removing olefinic impurities from hydrochlorofluorocarbons |
| US5395999A (en) * | 1992-11-06 | 1995-03-07 | E. I. Du Pont De Nemours And Company | Catalytic chlorofluorination process for producing CHClFCF3 and CHF2 CF3 |
| EP0844226B1 (en) * | 1993-03-05 | 2001-10-31 | Daikin Industries, Limited | Method of purifying 1,1,1,2,2-pentafluoroethane |
| IT1270959B (it) * | 1993-08-13 | 1997-05-26 | Ausimont Spa | Processo per la preparazione di pentafluoroetano |
| WO1995011875A1 (en) * | 1993-10-28 | 1995-05-04 | Alliedsignal Inc. | Process for purifying 1,1-dichloro-2,2,2-trifluoroethane and 1-chloro-1,2,2,2-tetrafluoroethane |
| US5928479A (en) * | 1994-04-08 | 1999-07-27 | Imperial Chemical Industries Plc | Process for the purification of pentafluoroethane |
| US5545778A (en) * | 1994-05-25 | 1996-08-13 | Alliedsignal Inc. | Single stage process for producing hydrofluorocarbons from perchloroethylene |
| US5569794A (en) * | 1994-05-24 | 1996-10-29 | Alliedsignal Inc. | Vapor phase process for producing hydroflourocarbons from perchloroethylene having a phenolic inhibitor |
| US5563304A (en) | 1994-05-26 | 1996-10-08 | E. I. Du Pont De Nemours And Company | Production of 1,2-dihydro and 2,2-dihydro hexafluoropropanes and azeotropes thereof with HF |
| US5414165A (en) * | 1994-07-29 | 1995-05-09 | E. I. Du Pont De Nemours And Company | Process for the manufacture of 1,1,1,3,3,3,-hexafluoropropane |
| WO1996015085A1 (en) * | 1994-11-14 | 1996-05-23 | Great Lakes Chemical Corporation | Process for production of 1,1,1,3,3,3-hexafluoropropane |
| KR0125143B1 (ko) * | 1994-12-02 | 1997-11-27 | 김은영 | 1,1,1-트리플루오로-2,2-디클로로에탄의 불소화 촉매 및 그것의 제조방법 |
| US5475167A (en) * | 1995-02-17 | 1995-12-12 | E. I. Du Pont De Nemours And Company | Process for the manufacture of pentafluoroethane |
| US6034289A (en) * | 1995-06-08 | 2000-03-07 | E. I. Du Pont De Nemours And Company | Treatment of chromium oxide and catalytic manufacture of vinyl fluoride |
| WO1997003936A1 (en) * | 1995-07-14 | 1997-02-06 | E.I. Du Pont De Nemours And Company | Distillation processes for removing cfc-115 and hydrofluoric acid from hfc-125 |
| FR2740994B1 (fr) | 1995-11-10 | 1997-12-05 | Atochem Elf Sa | Catalyseurs massiques a base d'oxyde de chrome, leur procede de preparation et leur application a la fluoration d'hydrocarbures halogenes |
| US6417413B1 (en) | 1999-11-03 | 2002-07-09 | Alliedsignal Inc. | Process for the preparation of halogenated ethanes |
| US6472574B2 (en) | 1999-12-10 | 2002-10-29 | E. I. Du Pont Nemours And Company | Production of 1,2-dihydro and 2,2-dihydro hexafluoropropanes and azeotropes thereof with HF |
| FR2807751B1 (fr) * | 2000-04-12 | 2005-05-20 | Solvay | Procede pour la preparation d'un hydro (chloro) fluoroalcane et catalyseur |
| JP2005536539A (ja) * | 2002-08-22 | 2005-12-02 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | １，１，１，２，２−ペンタフルオロエタンを製造するための方法 |
| CN100464840C (zh) | 2002-08-22 | 2009-03-04 | 纳幕尔杜邦公司 | 钴取代的氧化铬组合物,它们的制备以及它们作为催化剂和催化剂前体的用途 |
| US7129383B2 (en) * | 2002-08-22 | 2006-10-31 | E. I. Du Pont De Nemours And Company | Processes for the preparation of 2-chloro-1,1,1,2,3,3,3-heptafluoropropane, hexafluoropropene and 1,1,1,2,3,3,3-heptafluoropropane |
| DE60330789D1 (de) * | 2002-08-22 | 2010-02-11 | Du Pont | Nickelsubstituierte und gemischt nickel- und cobaltsubstituierte chromoxidzusammensetzungen, deren herstellung und deren verwendung als katalysatoren und katalysatorvorläufer |
| GB0525701D0 (en) * | 2005-12-17 | 2006-01-25 | Ineos Fluor Holdings Ltd | Process |
| GB0525702D0 (en) * | 2005-12-17 | 2006-01-25 | Ineos Fluor Holdings Ltd | Process |
| GB0525699D0 (en) * | 2005-12-17 | 2006-01-25 | Ineos Fluor Holdings Ltd | Process |
| GB0525700D0 (en) * | 2005-12-17 | 2006-01-25 | Ineos Fluor Holdings Ltd | Process |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU3717989A (en) * | 1988-06-29 | 1990-01-04 | E.I. Du Pont De Nemours And Company | Gas-phase hydrofluorination process |
| AU3861089A (en) * | 1988-06-23 | 1990-01-12 | E.I. Du Pont De Nemours And Company | Catalyzed hydrofluorination of alkenes |
| AU600212B2 (en) * | 1987-07-07 | 1990-08-02 | E.I. Du Pont De Nemours And Company | Gas-phase fluorination process |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2458551A (en) * | 1947-02-18 | 1949-01-11 | Du Pont | Preparation of carbon tetrafluoride |
| US2576823A (en) * | 1947-11-13 | 1951-11-27 | Du Pont | Fluorination with granular crf3 catalyst |
| US3258500A (en) * | 1959-08-17 | 1966-06-28 | Du Pont | Process for fluorinating halohydro-carbons |
| US3183276A (en) * | 1960-03-16 | 1965-05-11 | Edison Soc | Process for the production of fluorinated organic compounds |
| GB1000485A (en) * | 1962-02-07 | 1965-08-04 | Sicedison Spa | Improvements in or relating to the fluorination of halo-olefines |
| DE1910529C3 (de) * | 1969-03-01 | 1978-09-28 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur katalytischen Hydrofluorierung von bestimmten gesattigten und ungesättigten halogenierten Kohlenwasserstoffen |
| GB1307224A (en) * | 1969-06-27 | 1973-02-14 | Ici Ltd | Chromium oxide catalyst |
| JPS4872105A (en]) * | 1971-12-29 | 1973-09-29 | ||
| FR2501062A1 (fr) * | 1980-12-29 | 1982-09-10 | Ugine Kuhlmann | Catalyseurs de fluoruration en phase gazeuse de derives chlores aliphatiques, a base de microbilles d'oxyde de chrome, et procedes de fluoruration utilisant ces catalyseurs |
| IT1202652B (it) * | 1987-03-09 | 1989-02-09 | Ausimont Spa | Processo per la preparazione di 1,1,1-trifluoro-2,2-dicloroetano mediante idrofluorurazione in presenza di catalizzatori |
-
1987
- 1987-10-22 US US07/111,292 patent/US4843181A/en not_active Expired - Lifetime
-
1988
- 1988-10-12 MX MX013518A patent/MX165875B/es unknown
- 1988-10-17 IN IN863/CAL/88A patent/IN171034B/en unknown
- 1988-10-20 CA CA000580780A patent/CA1310022C/en not_active Expired - Lifetime
- 1988-10-21 KR KR1019880013781A patent/KR890006550A/ko not_active Ceased
- 1988-10-21 JP JP63265904A patent/JPH01146832A/ja active Pending
- 1988-10-21 DE DE3887625T patent/DE3887625T2/de not_active Expired - Fee Related
- 1988-10-21 RU SU884356764A patent/RU2007380C1/ru active
- 1988-10-21 AU AU24115/88A patent/AU609529B2/en not_active Ceased
- 1988-10-21 BR BR8805440A patent/BR8805440A/pt not_active Application Discontinuation
- 1988-10-21 EP EP88117532A patent/EP0313061B1/en not_active Expired - Lifetime
- 1988-10-21 ZA ZA887889A patent/ZA887889B/xx unknown
- 1988-10-21 ES ES88117532T patent/ES2063750T3/es not_active Expired - Lifetime
- 1988-10-22 CN CN88108415A patent/CN1014988B/zh not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU600212B2 (en) * | 1987-07-07 | 1990-08-02 | E.I. Du Pont De Nemours And Company | Gas-phase fluorination process |
| AU3861089A (en) * | 1988-06-23 | 1990-01-12 | E.I. Du Pont De Nemours And Company | Catalyzed hydrofluorination of alkenes |
| AU3717989A (en) * | 1988-06-29 | 1990-01-04 | E.I. Du Pont De Nemours And Company | Gas-phase hydrofluorination process |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU630807B2 (en) * | 1990-05-11 | 1992-11-05 | Atochem | Process for the manufacture of 1,1,1,2-tetra-fluorochloroethane and/or pentafluoroethane |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01146832A (ja) | 1989-06-08 |
| KR890006550A (ko) | 1989-06-14 |
| CN1033989A (zh) | 1989-07-19 |
| ES2063750T3 (es) | 1995-01-16 |
| DE3887625T2 (de) | 1994-07-14 |
| DE3887625D1 (de) | 1994-03-17 |
| MX165875B (es) | 1992-12-08 |
| CA1310022C (en) | 1992-11-10 |
| IN171034B (en]) | 1992-07-04 |
| AU2411588A (en) | 1989-04-27 |
| RU2007380C1 (ru) | 1994-02-15 |
| BR8805440A (pt) | 1989-06-27 |
| EP0313061B1 (en) | 1994-02-02 |
| ZA887889B (en) | 1990-06-27 |
| CN1014988B (zh) | 1991-12-04 |
| EP0313061A3 (en) | 1989-06-07 |
| US4843181A (en) | 1989-06-27 |
| EP0313061A2 (en) | 1989-04-26 |
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